Per Amazon, The DVD/BluRays will be released on August 19, 2014.
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Review from Amazon:
It’s a diabolical thing about curses: Just as one is broken, another, even more sinister than the first, inevitably emerges to wreak further havoc… Experience the heart-pounding action and tantalizing suspense of ABC’s ONCE UPON A TIME: THE COMPLETE THIRD SEASON. The stakes are higher than ever following a narrow escape from the nightmare of Neverland and Peter Pan. A year after their amazing adventure, Emma and Henry are living in New York with no aware of their past history — until Hook shows up and jogs Emma’s memory with a magic potion. Once again, the “Savior” is called back to Storybrooke when a legendary villainess arrives in disguise to curse the town anew and exact an unspeakably cruel vengeance. Now, with Regina and Emma working together, the stage is set for an epic showdown between the Evil Queen and the Wicked Witch of the West! Add season 3 to your ONCE UPON A TIME collection and relive all 22 captivating episodes. Plus, access never-before-seen bonus features. Each time you watch, you’ll fall deeper under the spell of this irresistible series.